Inorganic Chemistry III

Course Information
TitleΑΝΟΡΓΑΝΗ ΧΗΜΕΙΑ ΙΙΙ / Inorganic Chemistry III
Cycle / Level1st / Undergraduate
Teaching PeriodSpring
Course ID40002647

Programme of Study: PPS-Tmīma CΗīmeías (2016-sīmera)

Registered students: 187
OrientationAttendance TypeSemesterYearECTS
VASIKOS KYKLOSCompulsory Course6310

Class Information
Academic Year2018 – 2019
Class PeriodSpring
Faculty Instructors
Weekly Hours8
Class ID
Course Type 2016-2020
  • Scientific Area
Course Type 2011-2015
Specific Foundation / Core
Mode of Delivery
  • Face to face
Digital Course Content
The course is also offered to exchange programme students.
Language of Instruction
  • Greek (Instruction, Examination)
  • English (Examination)
Learning Outcomes
After completing this course, students will be able: • To handle with complex problems on composition and identification of complexes. • To Plan and execute the synthesis of complexes manipulating laboratory apparatus and laboratory instruments. • Operate spectrometers and other laboratory instruments and understand the basic principles governing the respective methods. • To present the results of laboratory studies in the form of written work. • To present research articles using audio-visual media.
General Competences
  • Apply knowledge in practice
  • Retrieve, analyse and synthesise data and information, with the use of necessary technologies
  • Work autonomously
Course Content (Syllabus)
Definition of ligand (monodantate, polydantate and chelating ligands) and coordination number; Coordination numbers and geometries; Chelate effect; Relation of geometries and symmetry (symmetry elements, crystal systems and character tables for chemically important symmetry groups); Nomenclature of coordination compounds; structural isomerism (geometrical, ionic, coordination, etc); stability constants and ligand exchange rates; Relation of electronic configuration with parmagnetism and diamagnetism; Spin-only moment; Electric conductance; Conductors, semi-condactors, non condactors; Theories of coordination compounds (Verner’s, Sidwick’s, Pauling’s valence bond theory theories, crystal field theory, ligand field theory and MO theory); Study of coordination compounds using spectroscopic and magnetic measurements techniques; Orgel and Tanabe-Sugano diagrams; Classification of coordination compounds (halide & pseudohalide complexes; aqua complexes; hydroxyl and oxo complexes; dioxygen and dinitrogen complexes; Complexes with oxygen and nitrogen donor ligands; carbonyl complexes, nitrozyl complexes; cyclopentadiene complexes); Syntheses of complexes (addition reactions, electron transfer reactions, ligand replacement reactions); Reactions of coordination compounds (metal based reactions, ligands based reactions, comples based reactions); Coordination compounds and applications; Study of complexes using spectroscopic and magnetic techniques) Laboratory exercises: Preparation of manganese, nickel and copper complexes with Schiff-bases ligands; preparation of nickel and Chromium complexes with dithiocarbamate and phosphine ligands; preparation of Chromium complexes with ethylenediamine, urea, isothiocyanate oxalate and ammine ligands; preparation of Cobalt complexes with pyridine and ammine ligands; preparation of Copper complexes with ammine, acetylacetonate and dithiocarbamate ligands; preparation of iron complexes with dithiocarbamate ligands; preparation of Cobalt complexes with amine ligands; study of the prepared complexes using IR and UV-Vis spectroscopic techniques; magnetic and molecular conductance measurements; spectrochemical series of studied ligands; structure determination using spectroscopic and magnetic measurements data; bibliographic search; oral presentation of research articles; homeworks.
Coordination chemistry, nomenclature, isomerism, symmetry, diamagnetism-paramagnetism, classification of coordination compounds, reactions, spectroscopic studies, applications, preparation and study of complexes, bibliographic search, oral presentation.
Educational Material Types
  • Notes
  • Slide presentations
  • Book
Use of Information and Communication Technologies
Use of ICT
  • Use of ICT in Course Teaching
  • Use of ICT in Communication with Students
Course Organization
Laboratory Work401.6
Reading Assigment1295.2
Written assigments100.4
Oral presentation60.2
Student Assessment
Student Assessment methods
  • Written Exam with Short Answer Questions (Summative)
  • Written Assignment (Summative)
  • Oral Exams (Formative)
  • Performance / Staging (Formative)
  • Written Exam with Problem Solving (Summative)
  • Report (Formative)
  • Labortatory Assignment (Summative)
Course Bibliography (Eudoxus)
Δ. Κεσίσογλου - Π. Ακρίβος: Χημεία Ενώσεων Συναρμογής" Εκδόσεις ΖΗΤΗ (2013), ISBN978-960-456-332-6
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