Learning Outcomes
Students during or after the successful completion of the course will:
- be able to understand physicochemical problems and the methodology of the Physical Chemistry
- be able to solve problems relevant to physical chemistry. Physical Chemistry is highly mathematical
- be able to understand the physicochemical phenomena that take place in various chemical and physical processes
- be able to apply analytic thinking in phenomena relevant to physical or chemical processes
Course Content (Syllabus)
Chemical kinetics:
The rate of a chemical reaction. Experimental methods in kinetics. Order of a reaction. Molecularity of a reaction. Opposing, consecutive and parallel reactions. Reac¬tion mechanisms. The Rate-determining step. The kinetics of complex reactions. The temperature dependence of reaction rates. The Arrhenius equation. Rate con¬stants and equilibrium constants. Collision theory of reactions between gases. Re¬action rates, calculation of rate constants from collision theory. Activated complex theory. Catalysis.
Electrochemistry:
Ionics. Liquid solutions. Ion solvation. The standard thermodynamic functions of ion formation in solu¬tions. The Arrhenius and Debye-Hückel theory. The ionic strength. Faraday’s laws and the electrochemical equivalent. Coulometers. Conductivity measure¬ments. Molar conductances. Transport numbers and mobilities. Electrodics. Defi¬nition of electrochemical potentials. Galvanic cells. Electromotive force (EMF) of a Cell. Free energy and reversible EMF. Entropy and enthalpy of cell reactions. Types of half-cells (Electrodes). Classification of cells. Standard electrode po¬tentials. Osmotic membrane equilibrium. Electrode kinetics. Polarization. Over¬potential. Applied electrochemistry. Some basic applications.
Colloidal Systems:
Optical, kinetic and electrical properties of colloidal systems. DLVO theory, stability of colloidal systems. Emulsions, microemulsions, foams, gels
Course Bibliography (Eudoxus)
Ν. Α. Κατσάνου, ΦΥΣΙΚΟΧΗΜΕΙΑ - ΒΑΣΙΚΗ ΘΕΩΡΗΣΗ, Εκδόσεις Παπαζήση, 1993
P. W. Atkins, ΦΥΣΙΚΟΧΗΜΕΙΑ, ΤΟΜΟΣ Ι+ΙΙΙ, ΠΑΝ. ΕΚΔΟΣΕΙΣ ΚΡΗΤΗΣ, Ηράκλειο, 1998
Additional bibliography for study
Δ. Α. Γιαννακουδάκη, ΦΥΣΙΚΟΧΗΜΕΙΑ, –πρώτου κύκλου, Εκδόσεις ΖΗΤΗ, Θεσσαλονίκη, 1981-82
Ν. Κουλουμπή, ΗΛΕΚΤΡΟΧΗΜΕΙΑ, Εκδόσεις ΣΥΜΕΩΝ, Αθήνα, 2005
P. W. Atkins, ΦΥΣΙΚΟΧΗΜΕΙΑ, ΤΟΜΟΣ Ι+ΙΙΙ, ΠΑΝ. ΕΚΔΟΣΕΙΣ ΚΡΗΤΗΣ, Ηράκλειο, 1998
J. W. Moore, PHYSICAL CHEMISTRY, PRENTICE-HALL, Fifth Edition, London, 1972
P. W. Atkins, PHYSICAL CHEMISTRY, OXFORD UNIVERSITY PRESS, Fourth Edition, Oxford, 1990