Learning Outcomes
During the course «Physics of surfaces and nanostructures” the students are expected to:
1. Understand the differences in the electronic properties of bulk materials, surfaces and nanoparticles
2. To get acquainted with the modern methods of growth and characterization of surfaces, thin films and nanostructures
3. To become familiar with the methods of fabrication of nanostructures
4. To bridge theory with practice using examples from the international literature
Course Content (Syllabus)
Course content
- Introduction to surfaces and nanostructures: Key differences from bulk materials. Representative applications (hydrophobic, biomimetic, and nanostructured surfaces; size effects; quantum confinement).
- Thermodynamic and electronic properties of surfaces: Energy cost for creating new surfaces, surface tension and energy, surface reconstruction, work function, electron affinity, surface states. Surface diffusion and oxidation.
- Thin films and semiconductor interfaces: Lattice strain and mismatch, quantum wells. Exercises and problems.
- Conditions of (ultra)high vacuum for the growth and characterization of nanostructures and clean surfaces: Features of ultra-high vacuum, basics of kinetic theory, conductivity in vacuum systems, types of pumps and vacuum gauges, material selection.
- Surface cleaning. Photolithography and its current advancements for the fabrication of nanostructures using top-down technology.
- Basics of nanostructure fabrication using bottom-up technologies: Epitaxial methods for the growth of thin films and nanostructures (molecular beam epitaxy, chemical vapor deposition, and their modifications).
- Techniques for the characterization of surfaces and nanostructures: Chemical composition (AES, XPS, SIMS, micro-XRF), surface structure and monitoring of monolayer film growth (LEED, RHEED).
- Synchrotron radiation and material characterization techniques: Non-destructive identification of nanostructures (EXAFS & SEXAFS) and electronic structure (NEXAFS,
UPS, ARUPS).
- Applications of nanomaterials and safety.
- Large-scale production and quality control of nanomaterials.
- Examples and applications from international literature. Review.
Keywords
surfaces, thin films, nanostructures, nucleation, growth methods, materials characterization, UHV, lithography
Additional bibliography for study
1. Σημειώσεις και διαφάνειες του μαθήματος που διατίθενται ηλεκτρονικά (https://elearning.auth.gr/course/view.php?id=6210)
2. “Introduction to surface and thin film processes” John A. Venables, Cambridge University Press
3. “Materials Science and Thin Films” Milton Ohring, Academic Press
4. “Physics at Surfaces” Andrew Zangwill, Cambridge University Press
5. “Solid Surfaces, Interfaces and Thin Films”, H. Lüth, Springer